A NEW CRYSTALLINE COMPOSITE ORGANIC CONDENSATE OF ALLIUM CEPA EXTRACT WITH STRONTIUM FERRITE MATERIAL

A NEW CRYSTALLINE COMPOSITE ORGANIC CONDENSATE OF ALLIUM CEPA EXTRACT WITH STRONTIUM FERRITE MATERIAL

K. L. Narayana

General Physics labs, Shivaji University,  Kolhapur - 416004.

&

K. S. R. Rao,

 The Rangadhamrao Foundation, Visakhapatnam.

ABSTRACT

The extract of Allium Cepa has been used to produce a new condensate (designated K) composite blended with strontium Ferrite (doped) polycrystalline material. Photomicrography morphological features revealed adducts of the Ferrite, in a ‘fluidous’ transport inside the veins and strands. The Infra-Red characterization, however, revealed the specific characteristics of the K-condensate organic composite material in the region of 4000 to 800 cm ^-1 wave numbers. The formation of it discovered by the functional group, amide- (C=O)-c-(CH-R)- NH that has been confirmed. The material is found to be Carcinogenous, extremely reactive and toxic. The physical transport characteristics of its electrical conductivity have been studied. Details of optical absorption and XRD analysis will be given.

------------------------------------------------------------------------------------------------------------

 7^th National Seminar on Crystal Growth, Anna University, Madras-0600025.  

        Dated 15-11-1996. D.D.No:  OT/F231587 UCO Bank Kolhapur Dt.7-11-96.

-----------------------------------------------------------------------------------------------------------------------

A NEW CRYSTALLINE COMPOSITE ORGANIC CONDENSATE OF ALLIUM CEPA EXTRACT 

WITH STRONTIUM FERRITE MATERIAL

K. L. Narayana

General Physics labs, Shivaji University, Kolhapur - 416004.

&

K. S. R. Rao

The Rangadhamrao Foundation, Visakhapatnam.

 7^th National Seminar on Crystal Growth, 

Anna University, Madras-0600025.  Dated 15-11-1996.

INTRODUCTION

     The cellular processes are rather complicated, but a careful analysis by different analytical techniques, one can identify the individual steps that lead to the generation of complex molecules and the organic moieties. The cytoplasma of a cell and the protoplasma lemma offer viscous colloidal systems of thixtropic gels. The degree of interaction depends on the changes in pH, temperature and the salts concentrations. Membrane bilayers and as well the thixtropic material consist of specific chemical groups that act as the substrates or the adduct regions, which obviously possess radical centers, that hold the inorganic and the organic crystalline structures.

        Our earlier studies on Polymer composites and thick films of copper phthalocyanins led to the utility of these materials to fabricate novel micro-electronic devices [1] and sensor systems [2]. Presently we report the incorporation of the Ferrite crystalline materials into the organic moieties. Characterization of the produced material is achieved by the X-ray diffraction, Optical and Infra-Red absorption studies. The Allium Cepa, in view of its remarkable ordered cellular block structures is found ideal for the production of the K-condensate material.

EXPERIMENTAL

                Fresh and healthy Allium Cepa extract obtained in a cold acetic-ethanol (1:3) medium has been refluxed in a Soxhlet apparatus. Appropriate concentration of the Ferrite semi-conducting material is then added with suitable additives (intellectual propriety right of authors) to the above said distillate. It is found that chemical molecular complexes will react with each other to form a precipitate. The composite material produced is then used for the characterization of the K-condensate phases.

Fig.1  The K-condensate Organic Composite material 

        For microscopic studies, it is found convenient to treat the Allium Cepa extract with acetic-ethanol (1:3) medium and the doped Ferrite material directly. At a higher magnification the mobile adducts, the protoplasm lemma and the cytoplasm thixotropic gel constituents could be observed. XRD, Infra-Red, and Optical spectra of the condensate have been then obtained.

RESULTS AND DISCUSSION

        The Infra-Red Spectrum of the lipid extract precipitate composite protein material [4, 5] confirmatively indicates the presence of amide band at 1650 cm^-1 and the one at 1535 cm^-1. The interesting fine structure of these bands immediately suggest that α-helical and β- conformations and as well the random coil conformation of the peptide chains. The presence of the band splitting with relatively distinct peaks about 1630 cm^-1 affirmatively suggest that there is an extensive β-structures present in the membrane structures. The presence of relatively good band at 1740 cm^-1 also points out the vibration Carbonyl stretching in fatty acid esters.

        The neatness of structures, around 550cm^-1 to 650cm^-1 confirms the inorganic Strontium Zinc Ferrite (doped) modification due to the amides of the peptide chains. Our additives (intellectual propriety right of authors) play a significant role. Olson and Manning (1976) have earlier stated that a large proportion of the randomly coiling phosphodiester linkages might adopt geometrical arrangements which tend to lengthen the chain end-to-end vector and also expose the attached bases to the aqueous solvents. All-trans character is associated with the lipid extracts while there is only little all-trans character of the CH₂ groups of lipid chains when they exist organized in a membrane. The interaction the Ferrite material with both, the anti-polar and polar amide acid residues of the protein composite material, results in the formation of the K-condensate phases. A description of the structure of this material immediately follows; since it is possible that overall structure of those complex molecules, tend to lead globular formations [6] in which the mega size ligands envelop the cationic Ferrite Moiety like the veins of Allium Cepa morphological surface. The utilization of the layer structure block of the aqueous solvent by the amide residual groups in the formation of the globular units is essential for the digestive mechanism of the organic material. The fine structure of the Infra-Red spectrum may then be inferred readily, as well due to the presence of Zweiger infinite chains. Alkali ions in such condensate phases lead to a remarkable degree of connectivity of the corner sharing tetrahedral structures. Also substituted species of the octahedral and trigonal bipyramidal of the K-condensate material leads to the existence of the said different phases.

        The strong radical band absorption at 1720 cm^-1 and 1780 cm^-1 are not evident and therefore protenoid formations is concluded to be less probable than the peptide bonds. Production of peptides by thermal copolymerization is known to understand pre biological [8] origin of protein. The role of Ferrite material [9] reveals in principle, how a variegated K-condensate phases, might be generated in an organic substance.

         K S R Rao         

An ardent Boy from Visakhapatnam committed to support his sisters

             

ACKNOWLEDGMENT

                     The author Prof. K. L. Narayana is particularly grateful to Late Prof. K. R. Rao D.Sc. (Madras), D.Sc. (London) diverse research guidance expertise at Andhra University, Waltair during the years 1932 to 1972 that enabled scores of students not only carry out research in different Science and Technology endeavors, but promoting most of them to go abroad and make a mark of the gained expertise. 

 REFERENCES

1. K. L. Narayana, “know Your Product”, Vol.2, No.10, p.25-31, Academician Bureau Publication, 101, Deepali 92 Nehru Place, New Delhi -110019, 1983.
2. K. L. Narayana, Nat. Symposium on High Polymers and Co-ordination Polymers, February 23-25, Paper No.HP-9, Department of Chemistry, Nagpur University, Nagpur, 1989.
3. D. T. Sawyer and P.T. Paulsen, J. Am. Chem. Soc, Vol.80, p.1577, 1958.
4. D. T. Sawyer and J. M. McKinnie, J. Am. Chem. Soc, Vol.82, p.4191, 1960.
5. C. S. Hanes, F. J. R. Hord, F. A.  Isherwood,  Biochem. J. Vol.51, p.25, 1952,
6. D. H. Gibson, Chem. Rev, p.2063-2095, 1996.
7. W. K. Olson and S. Manning, Biopolymers, Vol. 15, p.2391-2405, 1976.
8. (a). J. G. Lafontaine, J. Biophys. Biochem. Cytol, Vol.4, p.777, 1958. 
9. (b). C. J. Tandler, J. Histochem & cytochem, Vol.3, p.196, 1953
10.   K. L. Narayana, and P. M. Meshram, Paper No. 41 and 42, Section Physics, 84^th Sess. of  Ind. Sci.  Cong. Assoc, January 3-8, University of Delhi, New Delhi, 1997.